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Metallic Coatings

Metals are the most common materials for mirror fabrication. Polished metals, especially gold, copper and bronze, were used as mirrors in the ancient world. In the middle-ages, mirrors with relatively constant reflectance in the visible spectral range were fabricated using tin foils and mercury which were put on glass. The era of thin film metal coatings on glass began in the 19th century when Justus von Liebig discovered that thin films of silver can be manufactured using silver nitrate and aldehyde. For applications in precision optics and laser physics, mirrors are produced by using the evaporation or the sputtering technique.
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Fig.1:Reflectance of several metals versus wavelength (taken from Macleod [2])
LAYERTEC uses magnetron sputtering for manufacturing metallic coatings with extremely low scattering losses. Transparent, i.e. very thin, metal coatings can be produced with high accuracy. For detailed information about metallic mirrors and neutral density filters please see page Silver Mirrors for Ultrafast Lasers (550 – 1100 nm) and Front Surface Silver Mirrors (400 – 4000 nm). Fig. 1 gives an overview about the reflectance of the most common metals. In the following, we give some advice about the use of these metals and the role of protective coatings.

Silver

  • Highest reflectance in the VIS and NIR
  • LAYERTEC produces protective layers by magnetron sputtering. These layers with very high packing density make silver mirrors as stable as mirrors of other metals (e.g. aluminum). In normal atmosphere lifetimes of 10 years were demonstrated.
  • The use of protective layers is mandatory. Unprotected silver is chemically unstable and soft.
  • Please see separate data sheets on page Silver Mirrors for Ultrafast Lasers (550 – 1100 nm) and Front Surface Silver Mirrors (400 – 4000 nm).

Gold

  • Similar reflectance as silver in the NIR
  • Chemically stable, but soft
  • Protective layers are necessary to allow cleaning of gold mirrors
  • LAYERTEC recommends using protected silver mirrors instead of protected gold. The sputtered protective layers overcome the insufficiencies of silver. The broader wavelength range, the slightly higher reflectance and the favorable price also make silver the better option.
  • See separate data sheet about gold mirrors on page Special Metallic Coatings (400 – 10 000 nm).

Aluminum

  • Relatively high and constant reflectance in the VIS and NIR
  • Highest reflectance in the UV
  • Surface oxide layer absorbs in the deep UV
  • A protective layer is recommended because aluminum is soft
  • Please see separate data sheet on page Front Surface Aluminum Mirrors (150 – 900 nm).

Chromium

  • Medium reflectance in the VIS and NIR (R ≈ 40 % – 80 % depending on the coating process)
  • Hard (can be used without protective layer)
  • Good adhesive layer for gold and other metals on glass substrates

Protective Layers

  • Enable cleaning of optics and improve chemical stability
  • Influence the reflectance of the metal
  • Even very thin sputtered layers can be used for chemical protection of the metal because of the high atomic density of the layers. Such layers show minimal influence on the VIS and NIR reflectance of the metal.
  • Mechanical protection to enable cleaning of optics can only be achieved by relatively thick protective layer systems
  • Optimization of the protective layer system for the wavelength of interest is particularly necessary in the UV
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LAYERTEC GmbH
Ernst-Abbe-Weg 1
99441 Mellingen
Germany

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